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Cas no 7784-21-6 Aluminum hydride Inorganic compound 99% Other chemical raw materials

Aluminium hydride (also known as alane and alumane) is an inorganic compound with the formula AlH3. Alane and its derivatives are common reducing (hydride addition) reagents in organic synthesis that are used in solution at both laboratory and industrial scales.

In solution—typically in etherial solvents such tetrahydrofuran or diethyl ether—aluminium hydride forms complexes with Lewis bases, and reacts selectively with particular organic functional groups (e.g., with carboxylic acids and esters over organic halides and nitro groups), and although it is not a reagent of choice, it can react with carbon-carbon multiple bonds (i.e., through hydroalumination).

Given its density, and with hydrogen content on the order of 10% by weight, some forms of alane are, as of 2016, active candidates for storing hydrogen and so for power generation in fuel cell applications, including electric vehicles.[not verified in body] As of 2006 it was noted that further research was required to identify an efficient, economical way to reverse the process, regenerating alane from spent aluminium product.

Aluminum hydride, also known as alane, is an inorganic compound with the chemical formula AlH3. It is a colorless solid, soluble in THF and ether solvents, and is mainly used as a reducing agent.

Aluminium hydride info:

 
ChEBI
ChemSpider
PubChem CID
Molecular weight 
  • 30.005
Properties
AlH3
Molar mass 29.99 g/mol
Appearance white crystalline solid, non-volatile, highly polymerized, needle-like crystals
Density 1.477 g/cm3, solid
Melting point 150 °C (302 °F; 423 K) starts decomposing at 105 °C (221 °F)
reacts
Solubility soluble in ether
reacts in ethanol
Thermochemistry
40.2 J/mol K
Std molar
entropy
 (S298)
30 J/mol K
-11.4 kJ/mol
46.4 kJ/mol

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